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Miura, Daisuke*; Sekine, Yurina; Nankawa, Takuya; Sugita, Tsuyoshi; Oba, Yojiro; Hiroi, Kosuke; Ozawa, Tatsuhiko
Carbohydrate Polymer Technologies and Applications (Internet), 4, p.100251_1 - 100251_9, 2022/12
The reaction mechanism of carboxymethyl cellulose nanofiber (CMCF) hydrogel formed by freeze-crosslinking was investigated. We succeeded in observing the hierarchical structural changes during the freeze-crosslinking reaction. Freeze-crosslinked CMCF hydrogels exhibited a characteristic hierarchical alignment structure from the angstrom to micrometer scale that differed from normal cross-linked CMCF hydrogels produced by a conventional method without freezing. It was shown that the characteristic hierarchical structure contributes the excellent mechanical properties of freeze-crosslinked CMCF hydrogels.
glass up to 10 GPaUrakawa, Satoru*; Inoue, Toru*; Hattori, Takanori; Sano, Asami; Kohara, Shinji*; Wakabayashi, Daisuke*; Sato, Tomoko*; Funamori, Nobumasa*; Funakoshi, Kenichi*
Minerals (Internet), 10(1), p.84_1 - 84_13, 2020/01
Times Cited Count：9 Percentile：64.36(Geochemistry & Geophysics)The structure of hydrous amorphous SiO is fundamental to investigate the effects of water on the physicochemical properties of oxide glasses and magma. The hydrous SiO glass with 13 wt.% DO was synthesized under high-pressure and high-temperature conditions and its structure was investigated by small angle X-ray scattering, X-ray diffraction, and neutron diffraction experiments at pressures of up to 10 GPa and room temperature. This hydrous glass is separated into a SiO rich major phase and a DO rich minor phase. Medium-range order of the hydrous glass shrinks compared to the anhydrous SiO glass due to disruption of SiO
linkage by formation of Si-OD deuterioxyl, while the pressure response is similar. Most of DO molecules are in the small domains and hardly penetrate into SiO major phase.
Kobayashi, Taishi*; Nakajima, Shogo*; Motokawa, Ryuhei; Matsumura, Daiju; Saito, Takumi*; Sasaki, Takayuki*
Langmuir, 35(24), p.7995 - 8006, 2019/06
Times Cited Count：5 Percentile：22.5(Chemistry, Multidisciplinary)Narita, Hirokazu*; Suzuki, Tomoya*; Motokawa, Ryuhei
Nihon Kinzoku Gakkai-Shi, 81(4), p.157 - 167, 2017/04
Times Cited Count：17 Percentile：62.95(Metallurgy & Metallurgical Engineering)
-butyl phosphate in organic and aqueous environments and its relevance to nuclear extraction processesMu, J.*; Motokawa, Ryuhei; Williams, C. D.*; Akutsu, Kazuhiro*; Nishitsuji, Shotaro*; Masters, A. J.*
Journal of Physical Chemistry B, 120(23), p.5183 - 5193, 2016/06
Times Cited Count：27 Percentile：60.26(Chemistry, Physical)Motokawa, Ryuhei; Endo, Hitoshi*; Yokoyama, Shingo*; Ogawa, Hiroki*; Kobayashi, Toru; Suzuki, Shinichi; Yaita, Tsuyoshi
Langmuir, 30(50), p.15127 - 15134, 2014/12
Times Cited Count：27 Percentile：62.29(Chemistry, Multidisciplinary)Motokawa, Ryuhei; Endo, Hitoshi*; Yokoyama, Shingo*; Nishitsuji, Shotaro*; Kobayashi, Toru; Suzuki, Shinichi; Yaita, Tsuyoshi
Scientific Reports (Internet), 4, p.6585_1 - 6585_6, 2014/10
Times Cited Count：36 Percentile：70.26(Multidisciplinary Sciences)Yonezawa, Yasushige*; Tanaka, Shimpei*; Kubota, Tomomi*; Wakabayashi, Katsuzo*; Yutani, Katsuhide*; Fujiwara, Satoru
Journal of Molecular Biology, 323(2), p.237 - 251, 2002/10
Times Cited Count：76 Percentile：74.78(Biochemistry & Molecular Biology)It is known that hen egg white lysozyme (HEWL) forms amyloid fibrils in highly concentrated ethanol solutions. In order to gain an insight into the mechanism of the amyloid fibril formation, the structures of HEWL in solutions of various protein and ethanol concentrations were investigated with small-angle X-ray and neutron scattering. It was shown that the structural states of HEWL were distinguished as the monomer state, the state of the dimer formation, the state of the protofilament formation, the protofilament state, and the state towards the formation of the amyloid fibrils. Circular dichroism measurements showed that the large changes in the secondary structures of HEWL occurred during the dimer formation. Structural characterization showed that the dimers had an elongated shape, the protofilaments were formed by stacking of the dimers with their long axis (nearly) perpendicular to the protofilament axis, and the changes of the structural states towards the amyloid fibril formation occurred via lateral association of the protofilaments.
Suzuki, Kenji*; Kamiyama, Tomoaki*; Suzuya, Kentaro; Y.Wang*
Materia, 35(8), p.858 - 861, 1996/00
no abstracts in English
Ono, Hideo
Nihon Genshiryoku Gakkai-Shi, 36(7), p.607 - 610, 1994/00
no abstracts in English
Nihon Kessho Gakkai-Shi, 27(4), p.239 - 252, 1985/00
no abstracts in English
Journal of Non-Crystalline Solids, 51, p.367 - 380, 1982/00
Times Cited Count：10 Percentile：70.24(Materials Science, Ceramics)no abstracts in English
; Kuriyama, Isamu; *
Polym.J., 8(1), p.35 - 42, 1976/01
Times Cited Count：7no abstracts in English
Maekawa, Yasunari
no journal, ,
no abstracts in English
Maekawa, Yasunari; Zhao, Y.; Yoshimura, Kimio; Shishitani, Hideyuki*; Yamaguchi, Susumu*; Tanaka, Hirohisa*; Koizumi, Satoshi*
no journal, ,
no abstracts in English
Motokawa, Ryuhei; Endo, Hitoshi*
no journal, ,
no abstracts in English
Tominaga, Aki; Oba, Yojiro; Shobu, Takahisa; Owada, Kenji*; Tanida, Hajime; Konno, Azusa; Morooka, Satoshi; Motokawa, Ryuhei; Kumada, Takayuki
no journal, ,
In steel materials, it is known that precipitation of Cr rich phase hardens ferrite phase and decreases toughness in base material. Small angle X-ray scattering is a promising method for analysis of this precipitation process because the precipitate is nanometer size. However, it is usually difficult to separate the scattering between the Fe phase and Cr phase since Fe and Cr are close in atomic number. Therefore, in order to observe the state of phase separation of Cr, we developed an anomalous X-ray small angle scattering (A-SAXS) method at BL22XU.
Tominaga, Aki; Oba, Yojiro; Shobu, Takahisa; Tanida, Hajime; Owada, Kenji*; Konno, Azusa; Morooka, Satoshi; Motokawa, Ryuhei; Kumada, Takayuki
no journal, ,
In development of oxide-dispersed ferritic steels, it is known that precipitation of Cr rich phase hardens ferrite phase and decreases toughness in base material. Small angle X-ray scattering is a promising method for analysis of this precipitation process because the precipitate is nanometer size. However, it is usually difficult to separate the scattering between the Fe phase and Cr phase since Fe and Cr are close in atomic number. Therefore, in order to observe the state of phase separation of Cr, we developed an anomalous X-ray small angle scattering (A-SAXS) method using synchrotron radiation.
